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"Iron in Pool Water Problems"
The cause of most staining & discoloration problems.
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Iron
makes its presence known as a rusty or amber-brownish stains or even as a green
- amber - rusty-brown colored pool water. In certain areas, iron is a
fairly common pool water problem and is especially true, if the
water is sourced from a well. The discoloring pool problems are related to
the dissolved heavy metals, that are oxidized, as chlorine or shock is added. Iron can be treated with Mineral Treatment
Products (chelating agents). It is important to add an excess amount of
product, in order to make sure that enough has been added to treat all of the
iron and other problematic minerals. that might be present. Stain
avoidance treatment should be used, whenever a water analysis indicates even a
trace amount is present. An alternative
method of dealing with known iron and heavy metal problems is to use the
METALTRAP Filter, which can physically remove the metals, as the pool water is
being added.
Iron and other heavy metal
problems can treated with Pool Refresh, used in conjunction with other METALTRAP
products.
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The METALTRAP Filter will trap & remove iron,
copper and other heavy metals, from the pool water and from all new water
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testers require no color matching or look up charts and perform the
following tests: pH, Free & Total Chlorine, Bromine, Total Alkalinity,
Hardness, Cyanuric Acid, Iron, Copper, Biguanide & Biguanide Shock.
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Yikes It's Iron?
Alan,
when we opened the pool this year, and "yikes" for the first time ever, we
have rust all around the pool sides. The winter waterline down, but none on
the floor of the pool. Why would we have this problem now? Our water
source hasn't changed and it's not well water. Well,
my better half decided to put a mineral treatment in the pool (not a lot, but
it's still in there). Have we made a terrible mistake? Will our
chemical levels be out of whack all summer and will we be able to swim in the
pool? Now I am afraid to add any
of the chemicals from the pool opening kit. Please
help, thanks.
Karen from
Ohio, 6/10/2011
If the pool water problem is really iron,
adding an iron mineral treatment was the right thing to do! It is
possible for
trace amounts of iron to be present
in tap water. However , that should not have caused the problem. If
it is iron, it somehow made its way into
the pool. It could have been that the last time water was added, a fire
hydrant was opened in the neighborhood. This can lift sediments off the
bottom and deliver them to your pool. Try this. Put 1/2 pound of
pH reducer powder in a white sock, tie a string onto the sock and drape it
over the wall of the pool. Let it contact the stained area. If
improvement is seen, within 15-30 minutes, it is confirmation that the problem
is iron and/or other metals. Source unknown! It might be
necessary for you to lower the pH drastically to approximately 6. Use
the brush on the walls and keep the filter going. Afterwards, add a triple
dose of a quality mineral treatment, to help prevent a recurrence. When
everything is back to normal, backwash or clean the filter. This will help
prevent the material from being redissolved in the water. Yes, you will
be able to swim and the chemistry can be corrected.
To better assure proper
overall pool water chemistry, visit a pool store that has a very
reliable, professional lab such as a WaterLink or Pinpoint system,
rather than a less accurate test kit or strip reader.
To locate a dealer near
you, go to:
LaMotte Professional Testing Center Locator Good luck and I hope that
I have been helpful.
Sincerely.
Alan
Schuster, 6/10/2011
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Dealing With Iron, Before A Problem Happens?
I have close to 1 PPM of iron in the water, that
will be used to fill my pool, inground 20,000 gallon vinyl lined.
What should I do, to avoid problems with staining?
Jack B. Jackson, NJ, 7/23/2010
After the pool is filled, most of the
iron may be in solution and some may be in suspension.
POOL REFRESH,
is a 2-part product, that will help precipitate the iron and other heavy
metals,
so that they can be vacuumed and filtered to waste. Nothing beats,
physically removing the iron. And this will help remove any phosphates, as
well. After this is done, I would add a quart per 10,000 gallon
of
Liquid METALTRAP.
This true, phosphate-free, chelating agent will scavenge up any remaining
traces of heavy metals and keep them in a harmless state. Wait a day, for
the chelating agent to find all remaining
traces of heavy metals. During this entire process keep the filter going
24/7. Now, you're ready to adjust the water chemistry and sanitizer
levels. During the course of the season, it will be necessary to add
water, due to evaporation, splashout or backwashing. Use a
METALTRAP Filter,
connected to a garden hose to treat all new additions of water. The metals
will get trapped in this cartridge-like filter and be kept out of the pool
water. Next spring make sure that the METALTRAP Filter is used to treat
the new water. To add an additional degree of protection, each
spring add a quart of Liquid Metal trap, per 20,000 gallons, if the previous
steps were followed. This may sound complicated and tedious, but I
can assure you it is a lot simpler and less expensive that dealing with the
staining and coloration, that untreated iron and heavy metals can cause. Planning ahead was a wise thing to do.
Sincerely. Alan Schuster, 7/24/201 0
►
Do Some Metal Treatments Break
Down?
I have treated my pool with
products containing organic phosphonic acid and, while it seems to help, over
time the problem returns. Is this because the chemical breaks down?
Janet H., 8/9/2010
That type of product is known to degrade over time, allowing for a
return of the problem. As it degrades, it forms ortho-phosphate and that can
leave you with a phosphate problem. In addition, its effectiveness is limited,
if the pH is over 7.8. If you have a salt chlorine generator or plan to add
one, that type of product is not the best choice. A salt chlorine generators
tends to keep the pH at 7.8 or higher, unless daily attention is paid to the
pH. A product such as liquid METALTRAP is phosphate-free and is unaffected by
the pH of the pool. There are other METALTRAP products to help you remove
metals, from new water additions and products to remove stains. I hope that
this will help you resolve the issue.
Sincerely. Alan Schuster, 8/9/2010
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Iron
Stains?
There is an amber-brownish
colored stain in the deep end
of my vinyl liner, in-ground pool. According to the dealer, I have
0.2 PPM of iron. He is not sure that it is an iron stain. What
should I do? Thank you for any help.
G.F., Milton, PA, 7/14/2009
It is probable that the stain
is iron. We know there is iron present in the water and 0.2 PPM of iron is enough
to cause a pool water problem. First start by adding a dose of a quality Mineral
Treatment Product. This will chelate (complex) with iron and help prevent
further staining. To determine, if the stains can be removed with an
acidic solution try this: put a 1/2 pound of pH decreaser in a white sock and
drop onto a stained area. Leave in place for about 10 minutes. If
improvement is seen, as expected, a very practical method of removal would be to
use a stain-remover accessory. This gadget (available at many pool stores) will
allow you to siphon an acidic solution onto the stains. To make a suitable
solution: to a 1/2 gallon of water, in a plastic container, add 1 quart of a
quality Mineral Treatment Product and 1 quart of muriatic acid.
Make sure
that you wear rubber gloves and eye protection!
Use the stain-remover accessory to siphon the liquid onto the stains. If
the area is large you might want to allow the chlorine to bottom out and then
add ascorbic acid, as directed. Give it a day or two, before adjusting the pH
or adding chlorine, as
necessary.
There is another
non-chemical solution, to the problem. Using
the
METALTRAP, you
can treat all new water, which helps keep new additions of iron and other metals
out and minimizes the possibility of staining. You could, also, use The
METALTRAP to recirculate the pool water and lower the iron and heavy metal
content, already present in the pool water. I hope that these instructions will prove helpful.
Sincerely. Alan
Schuster, 7/15/2009
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Turned Brown?
Dear Alan, we have put up a small pool (2400
gallon) that was a kit from a local store, complete with a water pump/filter,
cover and such. Problem is we filled it from a well. The well is
known to have both iron and sulfur in the water. When I added the
initial set of chemicals (stabilizer, shock and chlorine) the water turned
real brownish in color. I presume (from one of your articles) it's because
of the iron, but I'm also wondering about the sulfur. Do I only need to
address the iron issue with a chelating agent, or do I need to do something
special for the sulfur too? Thanks and Regards,
Mitch, 5/18/2005
A quality mineral treatment
(chelating agent) is one of the proper treatment for the iron problem. It works best
before chlorine has been added or the pH has been increased. In fact, you
should to add the product as the pool is being filled. If you would
have used a
mineral removing filter, which
attaches to a garden hose, you might have been able to remove a lot of the
particulated iron and other metals. Using it on all future water
additions, also makes sense. A shock treatment
should take care of the sulfur. Make sure that there is a 1-3 PPM level of
Free Chlorine, that persists for an over night period. The sulfur will be
oxidized to harmless sulfates. I hope that I have been helpful.
Enjoy the pool.
Sincerely. Alan
Schuster, 5/19/2005
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Rusty-Brown Water?
The area that I live in has iron
in the water. Several times, in the past, I have had the pool water
suddenly turned rusty or brown, right after I added some chlorine. I'm
sure that it was because of the iron. The dealer had me treat the water
with a chemical and everything seems to be all right. Is there something
that I can do to avoid it from happening again?
Betty J., Littleton, MA,
6/2/2004
In all likelihood the dealer
had you add a Mineral Treatment, that was a chelating agent. This complexed
the iron and allowed it to remain in solution, without discoloration or
staining. From now on, it is important to add this chemical before any
make up water is added. In addition, I would add some every month, just
to make sure that there is an excess. The iron is still in the water:
it has been chelated and is now soluble and colorless and you want to keep it
that way. Springtime opening: add some more. Pool closing: add some
more. It may sound like overkill, but it will save you aggravation and the
possibility of staining and discoloration problems.
Considering that your water
is known to contain iron, there is another non-chemical solution, to the
problem. Using
the
METALTRAP Filter,
you can treat all new water, which helps keep new additions of iron and other
metals out and minimizes the possibility of staining. You could, also, use
The METALTRAP to recirculate the pool water and lower the iron and heavy metal
content, already present in the pool water.
In the long run you'll probably
save money too. I hope the advice does the trick.
Sincerely. Alan
Schuster, 6/2/2004
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Lots Of Rust?
I sure hope you can help, we
just purchased an above ground pool, we live in a small town in Illinois on
it's own well system the water is very hard and often has rust (iron oxide) in
it. We filled our pool using this water now we have the rust settled on
the bottom of the pool unless it gets stirred up then the water is brown and
nasty looking. What can we do to clean the water, we tried vacuuming the
bottom but the deposits are like a fine silt and only stirs not vacuuming up.
A rapid response would sure be appreciated my grandkids are so excited they
want to get in anyway, but I won't let them.
Diane M., Illinois, 6/11/2009
Avoid adding chlorine and
other chemicals right now. I suggest that you keep trying to vacuum as
much as possible through the filter and not to waste. Try adding a dose of
a "Blue" Clarifier; it should help coagulate the particles for easier
removal. Keep the filter operating non-stop. Try to get as much out
as possible and then backwash to waste or clean the filter. Before
adding chemicals, have the water tested for iron. For each 0.5 PPM of iron
or fraction, add a dose of a quality mineral treatment. Allow to circulate
for several hours
before adding
other chemicals. When adding new water, try and place the hose in the
skimmer to allow the filter an opportunity to remove the suspended iron.
Precede each new water addition with a dose of
mineral treatment and add another dose on a monthly basis.
Well water is almost
always a problem and there is a better solution, for the problem. You can
use a
METALTRAP Filter
to pre-treat all new water, which helps keep new additions of iron and other
metals out and minimizes the possibility of staining. You could, also, use
The METALTRAP to recirculate the pool water and lower the iron and heavy metal
content, already present in the pool water.
Well water can be a challenge and is
best when treatment is started early. Good luck. I hope that this
information is helpful.
Sincerely. Alan
Schuster, 6/11/2009
Alan,
Thank you for your help. A pool owner in our town said that they add pH minus to their pool
after filling it up and that clears it up after a couple of applications.
We put that in last night then an hour later we shocked, will this cause a
problem with the Blue? Thanks once again you are very helpful.
Diane, 6/11/2009
I was trying to help you get
the iron discoloration out of the water. Adding the pH minus will dissolve the iron and
it will remain in the water. The mineral treatment should complex the iron
and help keep it in a colorless and soluble state. You must add the
mineral treatment and add enough of it. Have the water tested for iron! You can add the "Blue" Clarifier,
the following day. Good luck.
Alan, 6/11/2009
Thanks so much, I've passed your information
on to the person that told me to use the pH minus so they can try the mineral
treatment instead. I loved your website.
Diane, 6/11/2009
►
Mineral Stain
Avoidance?
I plan on filling a 16,000 gallon
vinyl pool with water from my private well. I know that there is a low
level of manganese in the water. How should I treat the water after I fill
the pool up? I hope that you will be able to offer some advice.
Sincere thanks.
Don C.,
Westhampton, NY, 6/26/2004
Fortunately, you know that
there is manganese in the water. It would have been helpful to know how
much.
Testing for Iron and/or
Manganese is very important for planning a successful treatment.
Having lived on Long Island, I know what a problem manganese can be in some
pools on the south
shore. Those brown-black stains and discoloration are not great to look
at. In addition to having manganese, it is likely that the water has iron
and other minerals. Manganese is frequently associated with a purplish
discoloration or stain. The incidence of manganese problems, is for the
most part, limited to well water or corrosion of stainless steel. Both
iron and manganese can be treated along similar lines. As the water is
being fed into the pool, add 2 quarts of a quality Mineral Treatment for each 1
PPM of iron and manganese present in the fill water. Adding
more is better than adding less. After the pool has been filled,
recirculate the water for an hour. At this point, you can begin to adjust
the overall water chemistry. The early addition of the Mineral
Treatment should spare you from the problems associated with manganese.
Now, there is a better option!
Well water is almost
always a problem and there is a better solution, for the problem. The
METALTRAP
Filter enables you to pre-treat all new water, which helps
keep new additions of iron and other metals out of the pool water and minimizes
the possibility of staining. You could, also, use The METALTRAP to recirculate the pool water, lowering the iron
and heavy metal content, already present in the pool water.
The METALTRAP does it all and you
may not need any chemicals, depending on your water quality. Good luck and enjoy the season.
Sincerely.
Alan Schuster, 6/27/2004
►
Using Sodium Gluconate To Chelate Iron?
Please help.
I have a pool of 10,000 gallons of water and somehow a lot of iron has been
found in the water. Someone told me about
sodium gluconate.
Is this Ok to use in the pool water to chelate the iron? Also how much
would I need to use in 10,000 gallons of water and at what pH? Thank you.
Demetries, A., 10/27/2011
I have never heard of
sodium gluconate used in the pool industry, as a treatment for iron. It is
considered to be a chelating agent for iron, but at near neutral pH. At the
more alkaline pH, found in most pools, it is more apt to chelate the far more
abundant calcium. Therefore it would seem a poor choice. In
addition, I have no idea of how well it could survive in a chlorine-based pool.
On the other hand,
Liquid MetalTrap
will chelate iron, in the presence of chlorine and over the widest pH range,
that might be encountered. It is also phosphate-free. A MetalTrap
filter cartridge can be used, with a small submersible pump, to remove iron, as
the water passes through it. It can also be used to treat all new water
being added to the pool. I hope that you will find this information
helpful.
Sincerely. Alan Schuster,
10/7/2011
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