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Corrosive Pool Water Problems
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Avoiding destructive and irritating pool chemistry
problems.
The
Pool and Spa Informational Website askalanaquestion.com |
Causes,
Treatments and Solutions.
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Combating corrosive pool water starts with Water
Analysis, to gain control of the water chemistry.
Low pH and low Total Alkalinity and low Calcium
Hardness are parameters, that exert the major
effects. Refer to the
Langelier Index.
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Information. |
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How to treat and prevent
corrosive pool water conditions? Corrosive pool
conditions can cause a variety of pool problems
and should be avoided, by maintaining the water
chemistry as close to the optimum ranges, as
possible. Corrosion can result in damage to
underwater metal surfaces and equipment, damage
or even the destruction of copper heat
exchangers, etching of masonry pool surfaces,
wrinkle formation in vinyl liners and an
increase in the irritability of chlorine or
bromine pool water sanitizers. The corrosion of
metal parts can release, into the water, metal
ions that may lead to staining and/or
discoloration. Corrosive conditions can be
eliminated or controlled by the adjustment of
the pH, total alkalinity and calcium hardness.
Corrosion of Stainless Steel Ladders, Steps and
rails can be avoided, by the use of
maintenance-free, Composite products.
If problems arise, refer to the
Pool Problems Page, as
a source of problem-solving information, broken down into
various categories. Scroll down the page and click on the linked
keywords,
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or images, in the archived answers below, to access additional information, on that topic or product.
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Helpful,
Problem-Solving Information, in a question and
answer format.
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►
Copper Heater Corrosion?
Hi Alan, I
would like to know if ordering the ph
controller system would stop the problem I'm
having with my pool heater getting small pin
holes on the copper pipes. Would it be able
to fix my problem, if I order this unit?
According to the pool heater manufacturer,
the chemistry in the water is what causes
this problem.
Art, 12/7/2012
This pH Controller is not
a solution, for this situation, as it is
designed to lower the pH. Your problem stems
from having too low a pH, while chlorine or
bromine is present. Most likely, you are
using trichlor tablets in a feeder that is
not separately, from the heater by a check
valve or chlor is being used and the
resulting drop in pH is not being raised.
Trichlor is acidic and its use requires
regular addition of pH Increaser. It
is acidic conditions, with chlorine or
bromine present, that causes copper
corrosion. If you switch to a salt
chlorine generator, you will avoid the low
pH conditions, that lead to copper
corrosion. A salt chlorine generator raises
the pH, as chlorine is produced, so it is
unlikely there is will copper corrosion. If
you install a
salt
chlorine generator, you can make proper
use of the pH
Controller. I hope that this
information will prove helpful.
Sincerely.
Alan Schuster, 12/8/2012
► Pitting On The
Pool Ladder?
The ladder on my above the ground pool
is aluminum and has become pitted. What causes this and what
can I do?
J. M., 6/23/2012
Aluminum, if not suitably protected by a coating, can be
affected by swimming pool water. Low pH or high pH can
affect aluminum. Soft water conditions and low total
alkalinity can add to the problem. I don't know what the
useable life expectancy of your ladder is, but it should be
replaced, if there is a loss of structural integrity. There
are ladders, rails and steps made from composite materials,
that are better able to resist the problematic effects of
corrosion. Proper water chemistry matters, if you want to
help protect your investment and assure proper sanitation
and bather comfort. The ColorQ Digital Water Analyzers can
be used in all types of pools and with all types of
chemicals. With no color-matching or guesswork involved,
they have earned numerous best product awards. These
products are easy to maintain and do not require grounding,
making installation less complicated. I hope that I have
been of assistance.
Sincerely. Alan Schuster, 6/23/2012
► Ryznar
Stability Index?
What is the Ryznar Stability Index and
how does it help protect heaters and other equipment, from
corrosion?
Austin S., 8/15/2011
An article appeared in the 8/12/11 issue of Pool & Spa News
about the Ryznar Stability Index. This index is favored, by some
heater and equipment manufacturers, because it affords
greater protection against corrosion, than does the more
familiar Langelier Index. It favors higher calcium hardness
levels and/or higher pH levels. While this will lessen the
possible the corrosive effects of softer, lower pH water, it
comes at a price. It boosts the calcium hardness to a point,
where scale begins to form, which actually helps protect the
equipment, from corrosion. However, as scale forms in the
heater, it reduces the efficiency, by acting as an
insulator. In a filter, it acts to cement the filter media,
reducing the effectiveness of the filter. In areas of the
southwest, the water is already too hard, right out of the
tap and it is challenging to main a clear pool, without
excessive scaling. For more information, go to this website
page: Ryznar Stability Index I hope that this information
will help you better protect your pool equipment.
Sincerely. Alan Schuster 8/19/2011
► Corrosion
Concerns?
We are in the market for a pool. We
are trying to find out the facts on saltwater vs.
chlorinated pools. We had one guy trying to sell us a
saltwater pool. We were told by another pool builder that
they love saltwater pools, but stopped building them because
the water was eating up the coping.
Shawn M., 4/17/2007
There are millions of pools with
salt chlorine generators
out there and all have coping, of various types. My first
Lectranator salt chlorine generator usage was nearly 25
years ago. Possibly, there are some types that do not fare
well with salt chlorinated pools or any water with high
total dissolved solids (TDS. Some natural stones could be
ill-suited to use in any type of pool and should be avoided,
unless properly sealed against the elements. The problem is
that natural stones can vary considerably, even when the
names are the same. You are only adding 2500-3000 PPM of
salt: ocean water is 15 times higher. Some of the water in
Arizona and elsewhere contains 1500 PPM or more, right out
of the tap. A five year old pool on regular chlorine could
easily top 3000 PPM. High levels of chlorine, which salt
chlorine generators help avoid, is usually even more
damaging. I suggest discussing this with the builder.
Choosing a pool built of the right materials should
eliminate problems. It is easier to use and control, as
compared to standard chlorine products and that accounts for
its huge popularity. About 90% of pools in Australia, where
salt chlorine generator originated over 30 years ago, have
these units in operation and they use coping, decking and
everything else. Some coping, decking and stone features may
have to be sealed, with an appropriate product, to protect
them, not only from the effects of salt, but from the
effects of pool water and the elements, in general. I hope
that I have been helpful.
Sincerely. Alan Schuster, 4/17/2007
Editors Note: The following information is from
someone that I hold in high regard and is being added to
help shed more light on this subject.
My name is Sean Assam, with AquaCal AutoPilot Inc. I've been
in the industry for 20 years and have been exposed to almost
every facet of the pool industry. I am CPO certified. I
instruct classes in Water Chemistry and Testing Methods,
Pumps and Filters, and our own "Pool Pilot Flight School"
(all of which are approved continuing education credits,
required for Florida contractors). I was the Technical
Support Manager and R & D director for the last 5 years at
AutoPilot. Currently I do the Commercial sales and support
for Aqua Cal (Heat Pumps) and AutoPilot. So now I'm dealing
with large commercial systems on small and large public
pools, such as the Ritz Carlton Resorts, Hyatt Resorts, Four
Seasons, Marriott Hotels, etc. I'm sure if there were real
issues, these major facilities would not even consider salt
as an alternative to sanitizing their pools and spas.
For years, it seems that everything that has occurred
negatively to a pool has been blamed on salt systems. It
really does not matter that these same issues have been
around much longer than salt system, but salt has been the
convenient scapegoat. I'm not sure what may be causing the
coping or deck damage, but in my opinion, these problems are
regional and most likely have to do with the quality of the
deck material (limestone quarry) and cement mixture.
The contractors are mostly in Arizona and Texas. And while
the materials they use there are similar to materials used
nationally. It makes sense that even from the same quarry,
the quality can vary from high grade to low grade. If this
were a salt issue, the problems would be of national scale.
Salt systems have been around in the US since 1984, even
longer in Australia (1960's). Prior to AutoPilot purchasing
this company from The Olin Corporation, we were a
distributor of the Lectranator salt system. We've sold
several thousand systems in South Florida alone and I cannot
think of a single deck damaged pool that was contributed to
the salt system. Since we purchased the company in 1992,
we've sold over 100,000 units nationally, and another 50,000
units internationally. That's just one manufacturer in the
salt chlorination industry. Combined, there are over a
million salt systems installed in back yards all over the
US. Certainly, this would be a national epidemic, if it were
damaging. Yet, we're not seeing this, but on a few isolated
cases. I can say that none of these contractors, having
damage to their customer's pools, were AutoPilot dealers. If
so, I would have been personally called out to investigate
the problem. That's not to say that we're much different
than the others. Salt systems all operate in a similar
manner. I can say though that salt systems are being
unfairly blamed for these long standing issues. Some natural
materials are inappropriate to use with any pool and others
should probably be protected with a sealer.
Best Regards. Sean Assam, 4/18/2007
► Corrosion
of Stainless Steels Rails and Welds?
I am the Property Manager of a
condominium in Pennsylvania. The Pool that is in the
building is a Salt Water, Indoor, Stainless Steel Shell with
Tile over the Steel. Since day one (July 18, 2008) we are
experiencing rusting around all weld joints and hand
rails. The Pool Consultants are trying to say it is a
"stray current" going through the pool. Although I am not an
expert on Pools, I feel that the water in the Pool is not
balanced. Please help, it is embarrassing to have residents
swimming in a "rusty" pool. I believe it is a pH issue,
perhaps also that the piping was installed with all copper
instead of PVC and we lost two pumps to corrosion. I also
think it has something with the air temperature inside
the Pool room itself. Again, if you could be so kind and
help in anyway you would be my hero!
Michelle S., PA, 3/29/2009
 It could be a grounding issue and I suggest having this
checked. Salt chlorine generators tend to make the pH rise,
requiring regular additions of acid. High pH should not
corrode copper, even if chlorine is present. The rails or
welds could be of lesser quality materials and could be more
subject to rusting. There are composite rails, steps and
ladders that are unaffected by the water chemistry and do
not need grounding. Have the water tested for iron and
copper and treat, as needed. I hope that I have been
helpful.
Sincerely. Alan Schuster, 3/30/2009
► Avoiding
Corrosive Situations?
We have had a salt chlorinator for 3
yrs now. The first year was good, but we had trouble getting
our ladder and rails out at the end of the summer. The next
year was okay but we ended up having to cut the ladder and
rails off to get them out of the holes and had to buy new
ones. Last summer was real rainy at the beginning of the
summer season and we had a hard time regulating the pool
readings. The pool light casing was totally corroded and had
to be replaced and we, again, had a hard time getting the
ladder and rails out. Are we the only people who have had
these problems? Our pool company hasn't had many suggestions
for us and said they only have a couple of customers with
these types of problems. Any suggestions? Thank you.
Lori H., Michigan, 5/19/2009
Due to the drastic increase in the cost of nickel during the
past several years, stainless steel has become very
expensive . Manufacturers have attempted to save by using
lower grades of Stainless (less nickel), thinner walls (less
material), and by importing from China. China is currently
the main source of stainless steel pool rails sold in the
US. They are inexpensive, but for the most part of inferior
quality. That, combined with the increase in popularity of
salt chlorinators has led to many problems. You are not
alone by any means. I realize this is no consolation. Pools
that are over 15 years old are less likely to be affected,
as the quality of rails and ladders installed at that time
was superior to those that are on the market now. The older
ones are. therefore. less affected by salt or chemicals.
Unless one specifies marine-grade 316 Stainless Steel (which
is expensive and NOT the standard), a salt-chlorinated pool
that uses steel rails is very likely to degrade. In the
fine-print on the warranties of most stainless steel rails
and ladders, they all but guarantee that their rails will
corrode, if chemical balance isn’t precisely maintained at
all times. The above applies to any steel products in pools.
Most fittings and pool accessories are now made of plastics,
but rails, ladders and a few accessories like rims around
lights are holdouts. The only solutions are to either
A: Maintain PRECISE chemical balance in your pool at all
times.
B: Change your steel rails or ladders for a non-steel
alternative, such as products made of Composite Materials.
C: Find a manufacturer that can provide 316 Stainless if you
prefer the look of steel.
D: Expect to have to continue replacing your ladder every
two or three years.
Corrosion is not limited to pools with
salt chlorine
generators. Even pools, using ordinary liquid chlorine, will
have salt content that can rise quite high, after just a few
years. The key factor is to avoid corrosive chemistry, avoid
having two dissimilar metals in immediate proximity to one
another and choose a quality alternative, such as rails and
ladders manufactured of composite materials. I hope that
this information will be helpful, in understanding the
problem and making the right choice.
Sincerely. Alan Schuster, 5/19/2009
► Copper And
Heat Exchanger Corrosion?
Alan, my copper level at closing last
winter was 0.5 ppm, measured with a test kit. This occurred
when my second heat exchanger dissolved into the pool water.
(Long story - installer paid for his error and replaced
second heat exchanger). No copper ever added to pool on
purpose (i.e. no copper-based algaecide). After the first
heat exchanger was dissolved (like I said, a long story),
the entire plaster pool surface was stained blue-green.
Drain, acid wash, refill. Stain gone (all at installers
expense - at least he's honest). Now we're on the second
round. Problem root cause fixed, 3rd heat exchanger now in
place, but, as I said, 0.5 ppm copper remains from dissolved
heat exchanger number 2. Question: What's the best way to
get rid of the copper? I'd rather get rid of it than
sequester it. Naturally, I'd like to avoid another drain and
refill. I've heard that there are products that can remove
copper. Have you had any experience with this? pH is always
on the high side, around 7.6. I'm afraid the copper is going
to precipitate out any day now. My wife says she can see
little green spots on the white plaster. My eyes are not
that keen, but I want to nip this in the bud! I'm a
scientist and an engineer, so I like to know what's going
on, even if I let someone else do the work! Also, my
installer, though honest, needs some direction. Thanks for
your advice!
David S., Colts Neck, New Jersey, 4/25/2011 That's quite a story. Sounds like someone put a chlorinator
in front of the heater and this resulted in the corrosion of
the copper heat exchanger. The only way to deal with the
copper is by chelating the copper. This will complex the
copper and allow it to remain in solution, thereby avoiding
the risk of precipitation or discoloration. Mineral
Treatment products use the term "remove" in a very general
sense. They actually mean "helps control." These products do
not physically remove the copper. A concentration of 0.5 PPM
is comparable to that of a copper algaecide. By adding a
quality mineral treatment, such as phosphate-free,
Liquid
METALTRAP, you should be able to complex the copper and
avoid problems. Because this product will chelate all of the
heavy metals and to assure that enough product has been
added, I suggest that you add a double or triple dose.
Thereafter, add an initial dose each springtime opening.
Allowing the pH to remain at 7.6 or above, decreases the
solubility of copper and increases the likelihood of
staining and precipitation. To better assure proper overall
pool water chemistry, visit a pool store that has a very
reliable, professional lab such as a
WaterLink SPIN Lab or Pinpoint
system, rather than a less accurate test kit or strip
reader. To locate a dealer near you, go to:
LaMotte Professional Testing Center Locator I hope that I have been
helpful. Enjoy the season and the heater.
Sincerely. Alan Schuster, 4/25/2011
► Rising Salt
Level?
I recently bought a
Tracer
PockeTester, from your website. I am quite satisfied,
with the convenience and reliability of the tester, which I
use to monitor the salt levels in the pools, on my service
route, that have a salt chlorinator. While I like the
convenience of a salt chlorine generator, I never got around
to putting one on my pool, in the 3 years since it was
built. I use a combination of a trichlor feeder and lithium
shock. For no other reason, other than curiosity, I tested
the tap water and found a salt level or 600 PPM. That is not
uncommon or unexpected in this area. I then tested the pool
water and found a salt level of 2000 PPM. That came as a
major surprise, since I have never added any salt. Is there
an explanation?
Stephen S., 6/30/2010
Evaporation!!! There is nothing wrong with the
Salt
PockeTester, as I will explain. Finding high levels of salt
or TDS is nothing new and affects most pools, that are a few
years old. Assuming that you have a typical inground pool,
you can lose 2-inches of water a week. Possibly more, in the
summer, in a hot dry location. That 2-inch loss represents
2-3% of the water volume, depending on the presence and size
of the hopper area. Even allowing for rainfall to replenish
1/2 of the lose, you are still adding about 10 PPM of salt,
every time, you top off the pool, with the water containing
600 PPM of salt. 10 PPM a week, for 3 years, and you can
easily reach 2,000 PPM of salt: almost as much as some pools
with salt chlorine generators. Pump outs, splash outs and
backwashing will slow the rate of increase, However, no
matter what the salt level will rise substantially, over
time, when you are dealing with water than contains 600 PPM
of salt. If you were to use liquid chlorine the rate of salt
increase would be even higher. Measure your own average
weekly evaporational water loss and calculate the % lost.
Multiply this by the PPM of salt content of the new water
and you have the weekly rise in salt. You don't have to have
a salt chlorine generator to end up with salt in the pool.
The levels are not enough to taste, so it goes by unnoticed,
so long as the overall water chemistry is good. If the pool
did have the salt chlorine generator, with water containing
the appropriate amount of salt, the levels would rise even
more. When the salt level gets too high, water should be
replaced. Thank you for writing an for encouraging me to put
it to the numbers test.
Sincerely. Alan Schuster, 7/1/2010
► Salt
Corrosion?
I am a pool builder and am totally
sold on salt chlorine generators. They are great. However,
there is one sticky point I need to clarify with my
potential customers. Corrosion. As I am located in
Toronto Canada, we use salt on our roads in winter and it
rusts our cars over time. Everybody knows it. I know that
the levels are much higher than in a pool. Can you please
provide me with some data on the corrosive elements of a
salt chlorine generator, so I can answer these objections.
Any help would be greatly appreciated. Thanks.
Bill D., Toronto, Ontario, 3/4/2005
The parts of the cars that rust are made of ferrous metals
(steel) and possibly some other metals or alloys. There is
no doubt that salt will have a negative effect on cars.
However, pools are not made of ferrous metals. The salt add
to a salt chlorinated pool will only result in corrosion, if
two dissimilar metals are in immediate proximity to one
another. Without this relationship being present, there will
be no corrosion due to the salt. Even pools without a
salt
chlorine generators present, can have significant levels of
salt and TDS. Relentlessly, evaporation causes salt and TDS
level to rise. Pump, filter and accessory manufacturers have
long known about this problem and the newer products are
designed with the thought that a salt chlorine generator
might be in use. If the pool walls are steel, the liner
separates the water from the steel. Gunite pools have
finishes that are salt water tolerant and fiberglass pools
are completely unaffected. If the ring on an underwater
light is stainless steel and the screws that hold it in
place are chrome-plated brass, they will completely dissolve
over time. If the screws are stainless steel, there is not
longer a corrosion problem. The overall pool water chemistry
must be maintained within the accepted parameters, as with
any pool. Testing the salt level helps to get proper
performance and helps assure longer life for the salt-cell.
I hope that I have put your mind at ease. Sincerely. Alan Schuster, 3/5/2005
► When To
Replace Copper Pipes?
You've answered some pool questions
for me before and I trust you so I wanted to get your
opinion on this. We are getting estimates for new plaster
and possibly new pool decking right now. I was just told
that we need to replace the copper pipes with PVC before
re-doing the decking because copper will only last about 30
years (our house is 40 years old, swimming pool at least 30
years old) and they will start leaking soon and consequently
ruin the decking we put in. Is this true? Appreciate your
time & feedback.
Karen C., 2/11/2009
I don't know if you can assign a finite life to copper
pipes. Your contractor is trying to convince you to spend
some money now, while new decking is being installed, rather
than risk a much greater expense down the road, should the
pipes fail. In that respect, he is making you aware and
allowing you to decide. Thirty years might be reasonable,
but so much depends on how the pool was maintained. If the
pool was allowed to remain in acidic conditions, with
chlorine present, copper corrosion WILL occur. The longer
these conditions persist, the more corrosion occurs. If a
trichlor feeder was placed up stream of copper pipes,
corrosion could result. I assume that you have not owned the
pool, for these 40 years, and maintenance questions are
unknown. If it were my decision, I would opt to replace the
pipes. PVC pipes would allow you to use a
salt chlorine
generator, if you so decided. With copper pipes, the salt
might corrode any soldered joints. I hope that this
information is helpful.
Sincerely. Alan Schuster, 2/11/2009
► Why Not A
Low pH?
If chlorine works better at lower pH
readings, why not keep the pH lower than 7.2-7.6?
Anonymous, 5/3/2009
Chlorine does work better at a pH below 7.2. However, there
are consequences that will result. Corrosion can present a
problem below 7.0. As the pH falls below 7.2, chlorine can
become increasingly more aggressive and irritating. The pH
of the eye fluid is 7.6 and, as you move further away,
discomfort can increase. Depending upon the type of pool -
vinyl lined or masonry - corrosive low pH conditions can
cause surface etching, liner wrinkling and equipment damage.
A pH of 7.2-7.6, helps assure bather comfort, allows
effective sanitizing and helps avoid corrosion. I hope that
I have answered the question.
Sincerely. Alan Schuster, 5/3/2009
► Pool Liner
Wrinkles?
When my vinyl liner was installed a
few years ago, it nice and smooth. Today, I see some
wrinkles in one area. What's the cause?
Barry D., Cinc., OH, 7/13/2004
Two things come to mind. It is possible that the bottom has
undergone some shifting and/or settling over the past few
years and this has led to some wrinkling. Another
possibility is that corrosive, acidic water conditions have
caused the vinyl liner to increase water absorption and this
has led to a stretching of the liner and the wrinkles. Is it
possible that you have been keeping the pH too low? It is
important to maintain the pH in the 7.2-7.6 range for bather
comfort, sanitizer efficiency and to help protect the pool
equipment! Low pH can be quite common with the use of
trichlor tablets in an automatic chlorinator because the
product is acidic and requires regular pH
monitoring. Because the water looks good, many people tend
to neglect the pH. The practice of "dumping" in chemicals
and allowing them to remain on the bottom, for prolonged
periods, is not recommended. Acidic chemicals such as pH
decreaser, muriatic acid or cyanuric acid can create the
acidic conditions that can contribute to this problem.
Always take care to broadcast or distribute all chemicals,
so as to avoid local high concentrations and lessen the
likelihood of problems. I hope that I have been helpful.
Sincerely. Alan Schuster, 7/13/2004
► Rough
Surface, Grayish Color And Hives?
We have a gunite pool that was
installed last Spring (2003), and have had a company
servicing the pool since then. Our plaster has gotten
rougher, and is pitted around some of the marker tiles. Is
this normal aging (in one year) or what would be likely
causes? Also, we have areas in the plaster that have been
grayish since installation, but the pool company said that
was normal, what do you think? Last, my children and my
husband have experienced a hivish sort of rash, with extreme
itching, the last few times they were in the pool/spa, but
the pool serviceman said nothing he put in should cause
that. Any ideas? Thanks.
Brenda P., 5/3/2004
It sounds like corrosive water conditions: low pH. That
would explain the pitting and roughing u p of the surface. If
you have a heater, it could also explain the graying of the
surfaces. Acidic water conditions
cause chlorine to be more
aggressive and irritating and this fits it with what you are
describing. If your pool is being maintained on slow
dissolving chlorine tabs in a feeder, it sounds like little
or no attention is being paid to the pH. Have the pH total
alkalinity and calcium hardness tested. If you have a
heater, have the water tested for copper and add a couple of
doses of a quality metal treatment, such as phosphate-free
Liquid MetalTrap, at least 6 hours before
raising the pH. Proper chemistry won't repair the surface,
but should prevent a further worsening. No, this is not
normal! Hope the information helps.
Sincerely. Alan Schuster, 5/3/2004
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